作者： Janja Vidmar^{a, b}, Radmila Mila?i?^{a, b}, Janez Š?an?ar^{a, b}

^a Department of Environmental Sciences, Jo?ef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia

^b Jo?ef Stefan International Postgraduate School, Jamova 39, 1000 Ljubljana, Slovenia

 

摘要：As a consequence of their widespread use, titanium dioxide nanoparticles (TiO2NPs) have been released into the environment where they can act as stressors towards biota. For the assessment of the environmental impact of these NPs it is important to quantitatively determine their concentration, size distribution and the dissolved Ti fraction in different water samples. In the present work, a new analytical approach was applied for sizing and quantitative determination of TiO2NPs (anatase and rutile) and dissolved Ti in aqueous samples by the use of single particle inductively coupled plasma mass spectrometry (SP-ICP-MS). The accuracy of the quantification of TiO2NPs by SP-ICP-MS was verified by calculating the recoveries between the determined and expected Ti concentrations (90–100%). The size distributions of TiO2NPs calculated by SP-ICP-MS (108 ± 10 nm for rutile, 29 ± 2 nm for anatase) were in a good agreement with data obtained by TEM (96–106 nm for rutile, 21–38 nm for anatase) and DLS (117 ± 22 nm for rutile, 42 ± 30 nm for anatase). The influence of different dwell times on the sizing and quantification of nanoscale titanium dioxide was also examined. Low limits of detection for NP diameter (37 nm) and NP concentration (3.69 × 10− 3 ng Ti mL− 1 for rutile and 0.058 × 10− 3 ng Ti mL− 1 for anatase) were obtained. In order to apply the procedure developed for the sizing and quantification of TiO2NPs in environmental waters, the severe Ca isobaric interference at m/z 48 was overcome by measuring the Ti on m/z 47. It was demonstrated that the procedure optimized for the determination of Ti in environmental waters can be applied in the sizing and quantification of TiO2NPs in river water samples spiked with nanoscale anatase and rutile.